Journal of Anatolian Chemistry and Chemical Education Research

ISSN:2564-6206

Synthesis, characterization, catalytic activity of phenoxy-imine compound and metal(III) complexes


In this study, 2-((p-tolylimino)methyl)phenol compound was synthesized from the reaction of 2-hydroxybenzaldehyde and 4-methylaniline. The new phenoxy-imine ligand was obtained from the condensation reaction of 2-((p-tolylino) methyl) phenol with 1,2-bis(bromomethyl)benzene. The resulting phenoxy-imine ligand was obtained from metal complexes with Fe(III), Cr(III) and Ru(III) chloride salts. The structures of all synthesized compounds were characterized by spectral and thermal methods such as elemental analysis, electrolytic conductivity, magnetic susceptibility measurements and FT-IR, 1H and 13C NMR, UV-Vis, LC-MS/MS and TGA/DTA. In addition, catalytic properties of synthesized metal complexes were investigated. In general, it has been observed in catalyst Ru(III) complexes that trigger the highest product formation in the synthesized catalysts.


Keywords


Schiff Base, metal(III) complexes, catalyst

Author: Ali Çapan - Gökhan Ceyhan, Mehmet Sönmez
Number of pages: 1-14
DOI:
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Journal of Anatolian Chemistry and Chemical Education Research
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